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Top Pigment

Ultramarine Blue

PB29

Alternate Names

Ultramarine Blue Light

Ultramarine Blue Dark

French Ultramarine

Pigment Description

Of all the most essential colors of the palette, this one makes our short list. The synthetic version is God’s gift to painters as it replaces and in many respects, succeeds, the extremely expensive Lapis Lazuli. There is no other pigment quite like it—a transparent royal blue that leans violet. Where cobalt blue has a feeling of solidity, ultramarine sparkles like tanzanite. We’re grateful for the discovery of synthetic ultramarine as it's hard to imagine what it would be like to be without a deep, rich blue at the ready. Natural Ultramarine from Lapis Lazuli shares the same pigment code, however it tends to look quite different as an oil paint. We’ve given Natural Lapis a separate entry in the pigment notebook.

Synthetic Ultramarine is a phenomenal deep blue. It's transparent, dark in masstone, chromatic in tints, and varies a bit from a middle blue to an indigo-violet. We compared a handful of varieties in oils here.

There are many shades within this pigment code but there tend to be two main forms. Of the two, one is slightly more reddish than the other— the "redder" shade is more violet, and is often labeled Ultramarine Blue Deep. Alternatively, in the English world, paintmakers may name the redder version “French”. It has excellent lightfastness, however it does have a few tricks up its sleeve in oils. There is also something called ultramarine sickness which describes some changes that can occur to the paint. However there don't seem to be any viable alternatives, and for most intents and purposes ultramarine behaves itself. For some wildcards regarding ultramarine, see Golden's recent lightfastness testing.

Resources

PB29 pigment data from David G. Myers, The Color of Art Pigment Database, Artiscreation.com

Information about PB29 from Bruce MacEvoy, Handprint Guide to Watercolors, General information about this class of pigments from Handprint

CAMEO Materials Database: Conservation & Art Materials Encyclopedia Online, Museum of Fine Arts Boston. (Accessed June, 2025). Ultramarine Blue, Synthetic https://cameo.mfa.org/wiki/Ultramarine_blue,_synthetic. Museum of Fine Arts Boston.

Alfa Chemistry (n.d. Accessed June 2025). Ultramarine Blue (PB29) https://materials.alfachemic.com/major-products/ultramarine-blue-pb29.html,. Alfa Chemistry.

Ambrose, Trevor (2023, September 24). ASTM Lightfastness Testing for Oil Paints https://justpaint.org/astm-lightfastness-testing-for-oil-paints/. Just Paint, Golden Artist Colors.

Stats

Lightfastness

Excellent with slight caveats.

Overall ultramarine tends to be excellent and gets solid highest marks (all 8’s on the BWS). In Golden’s Lightfastness Testing on mixing whites in oils, Ultramarine Blue showed some unexpected behaviors in some Flake white formulations as well as failure in a Lithopone made with safflower oil. There was also a slide to LFII when it was combined with pure Zinc Oxide. These results suggest that choice of mixing white may matter for Ultramarine Blue. There were also a few surprises as to its reactivity in artificial simulations such as QUV and Xenon testing. While unrelated to lightfastness, this color is known to discolor in the presence of acids. It is also worth noting that the lightfastness may vary depending on the manufacturer, with some industrial suppliers listing 7-8, while artist suppliers may list all BWS 8's (highest marks).

Transparency

Transparent, Semi-Transparent

Some list as Semi-Transparent

Toxicity

Low Concern. No known hazards, however see note.

We were surprised to see a toxicity note on CAMEO on natural lapis lazuli which is chemically similar. See also SDS. Treat all pigments and paints with studio safety protocols.

Tinting

Medium

Dry Time

Many varieties take 2-7 days, may contain driers.

Since it is slow drier, it may contain driers.

Oil Content

Sources vary, Low to Medium, perhaps on the lower end of Medium.

Oddly enough oil content by volume can be moderately low. Source here. Mayer assigns it to the medium category for volume, with a score of 85. By weight it is 38-40g/100g of oil.

Particle Size

Very Fine

Chemical Name

complex sulfur-containing sodium aluminum silicate, or complex silicate of sodium and aluminum with sulfur or sodium alumino-sulphosilate

NaO.AlO.SiO.NaS, or Na-x[(Al,Si)₁₂]O₂₄(Sy)

Dry Pigments listing PB29

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