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Top Pigment

Brown Iron Oxide

PBr7

Alternate Names

Burnt Sienna

Burnt Umber

Raw Sienna

Raw Umber

Pigment Description

Deep brown, light brown, black brown, chocolate brown, red brown, chestnut, sable, and near black. This is one of the largest single-pigment paint categories in artists' oils. We think of this as brown earth.

Names for paints with PBr7 commonly include Burnt Siennas, Brown Ochres, Burnt Umbers, Raw Umbers, Violet Hematites, Burnt Yellow Ochres (which turn reddish), Raw Siennas, Cassel Earths, Van Dyke Browns, Turkey Umbers, and more. Each paint name has a sort of unofficial cannon of attributes associated with it.

We must briefly caution that burnt umber as well as other umbers may cause problems in oil painting. That goes beyond the scope of this entry so consult conservation experts for more.

Paints made with PBr7 can range from yellow, orange, red, brown, violet, or even greenish.

In terms of working properties the texture and the opacity can vary almost as much as the hues.

The Artist's Guide to Health and Safety has more information about health issues associated with Iron and Manganese, and if there are other impurities the relevant sections need to be consulted. Her updated work can be found through her site.

Finally, there is a disturbing trend wherein paint companies are making blends to emulate earth tones instead of using earth tones. Bear in mind that the blends used to emulate the earths will not have the same stability.

Resources

PBr7 pigment data from David G. Myers, The Color of Art Pigment Database, Artiscreation.com,

Elliott, Virgil. Traditional Oil Painting. Echo Point Books & Media, LLC, 2019. https://amzn.to/4nwIdzq,

Spurgeon, Tad. Living Craft: A Painter's Process. Mt. Airy, Philadelphia, PA: Zoetrope, 2018. Newer version available here: https://www.thomaskitts.com/page/36804/tad-spurgeons-living-craft,

Information about PBr7 from Bruce MacEvoy, Handprint Guide to Watercolors, General information about this class of pigments from Handprint

Stats

Lightfastness

Excellent

Generally this pigment is thought to be among the most lightfast. However Golden’s Lightfastness Testing in oils revealed a slight sensitivity in a particular Raw Umber to Flake White in linseed oil, though this may be brand dependent. In general PBr7 performed at the expected ASTM I. There are many forms and colors of PBr7 and we would expect them to perform at ASTM I as well.

Transparency

RU and RS, Semi-transparent

Toxicity

Thought to be in the category of lesser concern, however may contain impurities

May contain manganese and other impurities. The Artist's Guide to Health and Safety has more information about health issues associated with Iron and Manganese, and if there are other impurities the relevant sections need to be consulted. Her updated work can be found through her site. Treat all pigments and paints with studio safety protocols.

Dry Time

Varies

Varies. Umbers dry very quickly naturally (1-2 days). For other PBr7s, 2-7 days is fairly typical.

Oil Content

Varies, Low to Very High

Varies considerably depending on the pigment. By volume, Raw Umber particularly is a paint that requires a lot of oil. A chart by Williamsburg shows a comparison. Mayer also categorizes it as high oil volume with a score of 103, and there is general agreement. Mars Violet often has a fairly low requirement by volume, some say the lower end of medium depending on the particular pigment. Burnt Sienna can vary from medium to very high as well. Mayer assigns Raw Sienna a high oil volume with a score of 118, with Burnt Sienna at 129 and Burnt Umber at 136.

Chemical Name

Ferrosoferric oxide, calcined natural iron oxide containing manganese

Dry Pigments listing PBr7

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