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Blanc Fixe, Artificial Baryte

PW21

Alternate Names

Blanc Fix

Permanent White

Synthetic Barium Sulfate

Pigment Description

A common extender/filler in oil paints. A longer discussion of this pigment can be found under the related pigment code, PW22. These are closely related pigment numbers, however, the artificial kind (PW21) is said to have greater covering ability and has a finer consistency. Barium sulfate has different roles in water-based media (it is used in gouache) than oil-based media. In oil it has a low oil absorption, but is also linked to yellowing. In titanium white, It can actually contribute to the breakdown of the binder in oils due to light exposure and lead to problems like chalking, according to George O’Hanlon via this article. Seymour has an interesting discussion in the Artists’ Handbook of its complex relationship to opacity, as well as its weight, which can mislead artists into thinking a given tube of paint has a higher pigment load. This may particularly be a problem in more expensive colors where artists are looking for high pigmentation but can only go off of the feel of a paint tube to judge the quality. It is also used as a base in lake pigments.

Resources

PW21 pigment data from David G. Myers, The Color of Art Pigment Database, Artiscreation.com

Stats

Lightfastness

May interact with lightfastness

May speed up photocatalytic film degradation in oils, may also affect lightfastness of certain pigments. More research needs to be done

Transparency

Opaque in gouache, Transparent in oil

Has a complex relationship to opacity in oil

Toxicity

Possible Hazard, Can contain toxic impurities

May contain toxic soluble barium if it is not made with high standards, in which case that could be quite hazardous. Monona Rossol's research also states that PW22 and PW21 may contain other toxic impurities along with soluble barium. Her book, The Artist's Guide to Health and Safety, also has sections on the health hazards associated with barium, and we recommend consulting her latest work through her website. Treat all pigments and paints with studio safety protocols.

Dry Time

Slow

Oil Content

Low

Low by volume. By weight, Artiscreation lists 15-25g/100g of oil.

Chemical Name

Barium Sulphate (alternate spelling barium sulfate)

BaSO

Dry Pigments listing PW21

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