Blanc Fix
Permanent White
Synthetic Barium Sulfate
Process White
A common extender/filler in oil paints. A longer discussion of this pigment can be found under the related pigment code, PW22. These are closely related pigment numbers, however, the artificial kind (PW21) is said to have greater covering ability and has a finer consistency. Barium sulfate has different roles in water-based media (it is used in gouache) than oil-based media. In oil it has a low oil absorption, but is also linked to yellowing. In titanium white, It can actually contribute to the breakdown of the binder in oils due to light exposure and lead to problems like chalking, according to George O’Hanlon via this article. Seymour has an interesting discussion in the Artists’ Handbook of its complex relationship to opacity, as well as its weight, which can mislead artists into thinking a given tube of paint has a higher pigment load. This may particularly be a problem in more expensive colors where artists are looking for high pigmentation but can only go off of the feel of a paint tube to judge the quality. It is also used as a base in lake pigments.
PW21 pigment data from David G. Myers, The Color of Art Pigment Database, Artiscreation.com,
Rossol, Monona. The Artist's Complete Health and Safety Guide. New York, NY : Allworth Press, 2001. The book is rather dated, updated information is available from her website.
The pigment may interact with the lightfastness of other pigments, needs more research
May speed up photocatalytic film degradation in oils, may also affect lightfastness of certain pigments. More research needs to be done
Transparent, Opaque in Water
Has a complex relationship to opacity in oil
Possible Hazard, Can contain toxic impurities
May contain toxic soluble barium if it is not made with high standards, in which case that could be quite hazardous. Monona Rossol's research also states that PW22 and PW21 may contain other toxic impurities along with soluble barium. Her book, The Artist's Guide to Health and Safety, also has sections on the health hazards associated with barium, and we recommend consulting her latest work through her website. Treat all pigments and paints with studio safety protocols.
Slow
Barium Sulphate (alternate spelling barium sulfate)
BaSO₄
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