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Benzimidazolone Orange H5G

PO62

Pigment Description

Benzimidazolone Orange H5G, one of the more interesting modern oranges. This is a color that turns up in a handful of the attempts to replace Cadmium Orange, though the Benzimidazolone Orange we've tried has a yellow note in it. PO62 doesn't have the same high chroma as a cadmium orange PO20, nor does it have the same opacity. However, setting the cadmium discussion aside, in its own right this is an interesting pigment.

A bit of orange oil paint pulled back and forth by a palette knife

Gamblin Permanent Orange, PO62

From a health and safety standpoint it may metabolize to a mutagen, and or cause a condition called methemoglobinemia. Author Monona Rossol has more on this, so please consult her work for additional information.

Orange oil paint made with PO62 pulled with a palette knife to illustrate semi-transparency

Gamblin Permanent Orange, made with PO62 has some semi-transparency

Benzimidazolone Orange seems to have good lightfastness overall with a slight fall off in tints- we wish it were even a little more lightfast as it's a nice, not-quite-highest-chroma orange. Even though Gamblin describes this color as the same masstone as Cadmium Orange, we'd actually have to disagree based on their version of it, which does not quite share the same high chroma as most of our samples of PO20. We'd say this color is slightly less chromatic than cadmium orange.

A bottle of orange pigment from Schmincke

Schmincke Dry Pigment, just called "Orange," made of PO62

Resources

PO62 pigment data from David G. Myers, The Color of Art Pigment Database, Artiscreation.com

Information about PO62 from Bruce MacEvoy, Handprint Guide to Watercolors, General information about this class of pigments from Handprint,

Rossol, Monona. The Artist's Complete Health and Safety Guide. New York, NY : Allworth Press, 2001. The book is rather dated, updated information is available from her website.

Stats

Lightfastness

Very Good

Listed as ASTM I, but with BWS scales that show slight change (7 out of 8) in tints. In watercolor, Bruce MacEvoy found it to be excellent.

Transparency

Semi-Transparent, Semi-Opaque

Toxicity

Previously thought to be in the category of Low Concern, new research suggests this may be a mutagen and also metabolize to cause a serious health condition.

May metabolize to a mutigen, and may cause methemoglobinemia. See Monona Rossol's research available upon request here for more information. Treat all pigments and paints with studio safety protocols.

Dry Time

Medium

Particle Size

Fine

Chemical Name

monoazo, acetoacetyl, H5G, monoactolone

with PO62 (Benzimidazolone Orange H5G)
No single-pigment Oil found with PO62

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